这里的that是代词，“那件事或者那个东西”的意思，在句中作said的宾语。整个句子的意思是“他说那件事情，就好像他到过那里似的”。这里不要把that当成是引导宾语从句的引导词，形式上像，但实际上不是。
He said that as if he had been there.
句子结构不对呀。
that引导的宾语从句结构不完整。
可以改为：He said that it seemed as if he had been there.
或者：He felt as if he had been there.
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