(1)a-2(2a+b)+3(a-b)=a-4a-2b+3a-3b=-5b,当b=2时,原式=-5×2=-10;(2)-2(m2+mn)+3(n2-mn)=-2m2-2mn+3n2-3mn=-2m2-5mn+3n2,当m= 1 4 ,n= 1 2 时,原式=-2×( 1 4 )2-5× 1 4 × 1 2 +3×( 1 2 )2=- 1 8 - 5 8 + 3 4 =0.